Pensum/l?ringskrav

Organisk kjemi

John McMurry: Organic Chemistry, 2004. Thomson/Brooks/Cole. ISBN:?0-534-38999-6. 6. Utgave.

Tore Benneche: Laboratoriekurs - Organisk del, 2006. UiO, Kjemisk institutt.

F?lgende avsnitt i l?reboken inng?r i pensum:

Kap. 15 Benzene and Aromaticity (21 sider)

  • 15.1. Sources of aromatic hydrocarbons
  • 15.2. Naming aromatic compounds
  • 15.3. Structure and stability of benzene
  • 15.4. Molecular orbital description of benzene
  • 15.5. Aromaticity and the Hückel 4n+2 rule
  • 15.6. Aromatic ions
  • 15.7. Aromatic heterocycles: Pyridine and pyrrole
  • 15.8. Why 4n+2?
  • 15.9. Polycyclic aromatic compounds: Naphthalene
  • 15.10. Spectroscopy of aromatic compounds

Kap. 16 Chemistry of Benzene: Electrophilic Aromatic Substitution (32 sider)

  • 16.1. Bromination of aromatic rings
  • 16.2. Other aromatic substitutions
  • 16.3. Alkylation of aromatic rings: The Friedel-Crafts reaction
  • 16.4. Acylation of aromatic rings
  • 16.5. Substituent effects in substituted aromatic rings
  • 16.6. An explanation of substituent effects
  • 16.7. Trisubstituted benzenes: additivity of effects
  • 16.10. Oxidation of aromatic compounds
  • 16.12. Synthesis of trisubstituted benzenes

Kap. 18 Ethers and Epoxides; Thiols and Sulfides (16 sider)

  • 18.1. Naming ethers
  • 18.2. Structure, properties, and sources of ethers
  • 18.3. The Williamson ether synthesis
  • 18.6. Reactions of ethers: Claisen rearrangement
  • 18.7. Cyclic ethers: Epoxides
  • 18.8. Ring opening reactions of ethers
  • 18.10. Thiols and sulfides
  • 18.11. Spectroscopy of ethers

Kap. 19 Aldehydes and Ketones: Nucleophilic Addition Reactions (33 sider)

  • 19.1. Naming aldehydes and ketones
  • 19.2. Preparation of aldehydes and ketones
  • 19.3. Oxidation of aldehydes and ketones
  • 19.4. Nucleophilic addition of aldehydes and ketones
  • 19.5. Relative reactivity of aldehydes and ketones
  • 19.6. Nucleophilic addition of H2O: Hydration
  • 19.7. Nucleophilic addition of HCN: Cyanohydrin formation
  • 19.8. Nucleophilic addition of Grignard reagents and hydride reagents: Alcohol formation
  • 19.9. Nucleophilic addition of amines: Imine and enamine formation
  • 19.11. Nucleophilic addition of alcohols: Acetal formation
  • 19.12. Nucleophilic addition of phosphorus ylides: The Wittig reaction
  • 19.14. Conjugate nucleophilic addition of α,β-unsaturated aldehydes and ketones
  • 19.16. Spectroscopy of aldehydes and ketones

Kap. 20 Carbocylic Acids and Nitriles (20 sider)

  • 20.1. Naming carboxylic acids and nitriles
  • 20.2. Structure and physical properties of carboxylic acids
  • 20.3. Dissociation of carboxylic acids
  • 20.4. Substituent effects on acidity
  • 20.5. Substituent effects in substituted benzoic acids
  • 20.6. Preparation of carboxylic acids
  • 20.7. Reactions of carboxylic acids
  • 20.8. Reduction of carboxylic acids
  • 20.9. Chemistry of nitriles
  • 20.10. Spectroscopy of carboxylic acids and nitriles

Kap. 21 Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution Reactions (25 sider)

  • 21.1. Naming carboxylic acid derivatives
  • 21.2. Nucleophilic acyl substitution reactions
  • 21.3. Nucleophilic acyl substitution reactions of carboxylic acids
  • 21.4. Chemistry of acyl halides
  • 21.5. Chemistry of acid anhydrides
  • 21.6. Chemistry of esters
  • 21.7. Chemistry of amides

Kap. 22 Carbonyl Alpha-Substitution Reactions (20 sider)

  • 22.1. Keto-enol tautomerism
  • 22.2. Reactivity of enols: The mechanism of alpha-substitution reactions
  • 22.3. Alpha halogenation of aldehydes and ketones
  • 22.5. Acidity of alpha hydrogen atoms: Enolate ion formation
  • 22.6. Reactivity of enolate ions
  • 22.8. Alkylation of enolate ions

Kap. 23 Carbonyl Condensation Reactions (20 sider)

  • 23.1. Mechanism of carbonyl condensation reactions
  • 23.2. Condensation of aldehydes and ketones: The aldol reaction
  • 23.3. Carbonyl condensation reactions versus alpha-substitution reactions
  • 23.4. Dehydration of aldol products: Synthesis of enones
  • 23.5. Using aldol reactions in synthesis
  • 23.6. Mixed aldol condensation
  • 23.7. Intramolecular aldol condensation
  • 23.8. The Claisen condensation reaction
  • 23.9. Mixed Claisen condensation
  • 23.10. Intramolecular Claisen condensations: The Dieckmann cyclization
  • 23.11. The Michael reaction

Totalt 187 sider

Generell og uorganisk kjemi

Kap. 1 til og med kap. 9 i Geoff Rayner-Canham and Tina Overton: Descriptive inorganic chemistry, W.H.Freeman and Co., New York. Fourth edition.

Pavel Karen: Laboratoriekurs, uorganisk del, 2006. UiO, Kjemisk institutt.

Publisert 7. juni 2006 16:43 - Sist endret 28. aug. 2006 14:14